Black coating on oranges/grapefruit is sooty mold—fungi growing on honeydew excreted by sap-sucking insects (whiteflies, aphids, scale). The mold doesn't penetrate peel or affect flesh; it's purely cosmetic.
Cleaning fruit is temporary. Control the insects:
Sooty mold is harmless to eat. The bleach dip is the only method that reliably cleans deep peel crevices.
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