Yellow rainwater signals contamination—likely from roofing materials, gutters, pollen, or organic debris. Without knowing your collection system, it's impossible to identify the exact cause, but do not use it on carnivorous plants.
Clean your collection barrel/bucket with a mild sanitizer and rinse thoroughly. If collecting from roof/gutters, consider a first-flush diverter or switch to a cleaner catchment surface. When in doubt, use distilled, RO, or known-clean rainwater.
Rule of Thumb: Water for carnivorous plants should be colorless, odorless, and low-mineral (<50 ppm TDS). Yellow water fails the test.
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