Your husband is right: female dog urine burns lawn spots more noticeably than male urine. The reason is behavioral, not chemical. Female dogs squat and concentrate their urine in a small area, while males "sprinkle" over a wider territory. The high salt concentration in dog urine kills grass when deposited in a concentrated spot—male dogs would cause the same damage if they urinated the same way.
Train your dogs to use a designated relief area (mulch or gravel) to keep your lawn spot-free. Consistent training and an appropriate substrate solve the problem without restricting your pets.

Lola
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