Seedless watermelons are triploid (3x) hybrids created by crossing a tetraploid (4x) parent with a diploid (2x) parent. The resulting seeds are sterile, producing fruit with only small, white, edible seed coats.
Colchicine treatment requires precise laboratory conditions. Maintaining pure tetraploid and diploid lines, controlled pollination, and seed production is commercially specialized. The "seedless" seeds you buy are the triploid seeds from this cross.
White seed coats in the fruit are aborted ovules—edible and harmless.
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