Both poison ivy (Toxicodendron radicans) and native climbing hydrangea (Decumaria barbara) have conspicuously hairy vines. The key difference: climbing hydrangea leaves are opposite; poison ivy leaves are alternate.
Climbing hydrangea

Poison ivy

Poison Ivy Galls: Identification and Safe Removal
Chipping Poison Ivy Vines: Safety First
Orange Oil for Poison Ivy: Safer Alternatives Exist
Ivy on Trees: Why English Ivy Should Be Removed from Trunks
Poison Ivy Identification: Pictures and Look-Alikes
Poison Ivy Control: Identification, Herbicides, and Manual Removal
Selective Poison Ivy Control in English Ivy Groundcover
Poison Ivy in Mulch: Identification, Removal & Prevention
English Ivy on Pine Trees: A Deadly Combination
Concord Grape Vine Frozen to Ground: Will It Recover?
Identifying a Thorny, Three-Leaved Plant: Poison Ivy or Something Else?
Poison Ivy in the Garden: Identification, Removal & Home Remedies
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