Glyphosate and triclopyr effectively kill English ivy, but patience is the critical ingredient. You won't see damage for weeks because ivy grows in layers—initial sprays only reach upper leaves. I spray every three weeks to maintain a three-foot ivy-free zone along my fence line.
For large, flat ivy patches, mow as low as possible first, then spray emerging sprouts in a few weeks. Herbicides do work—the key is understanding the delayed visual response and maintaining consistent follow-up.

I keep this strip at my property line clear of English ivy
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Controlling Invasive English Ivy Without Harming Trees
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Controlling "Lawn Ivy" with Non-Selective Herbicide
Diagnosing and Treating English Ivy Decline Caused by Excess Moisture
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Poison Ivy Control: Identification, Herbicides, and Manual Removal
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