Azaleas, rhododendrons, and camellias prefer acidic soil, but the idea that they require rainwater is a myth. Tap water is perfectly fine for most gardeners.
While rainwater is naturally soft and slightly acidic, municipal tap water's dissolved solids (calcium, magnesium) are quickly leached from well-draining, organic-rich soil. Unless your water is extremely alkaline (high pH) and you have heavy clay, tap water won't harm these plants.
If you have a rain barrel, by all means use it—but don't stress if you don't.
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