Roundup (glyphosate) applied twice during active growth (temps >80°F) with a month between applications will kill centipede. Any surviving roots will invade the new St. Augustine sod.
Once centipede is dead, lay St. Augustine sod. There's no easy selective herbicide for centipede in St. Augustine. Do it right the first time.
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Troubleshooting Yellowing in New Centipede Sod
Weed Control in Centipede: Organic Myths vs. Reality
Organic Weed Control for Centipede Grass: The Sugar Method
Converting a Mixed Centipede and Bermuda Lawn to a Single Species
Removing Centipedegrass From St. Augustine Lawn
Acorns on the Lawn: Harmless Nuisance or Real Problem?
Grub Damage in Late Summer: Identification and Next Steps
Controlling Moss in Shady Lawns: The Limestone Solution
Growing Grass in a Small, Heavily Shaded Yard
Purple Streaks in Centipede Lawn: Traffic Stress, Not Disease
Centipede Grass Thinning in Shade: Fescue May Still Struggle
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