Your description (thick cane-like stems, brittle branches, 6-inch asymmetrical heart-shaped leaves with white spots) suggests a cane begonia—non-toxic. If no flowers, consider croton, gold dust dracaena, polka dot plant, or caladium—all toxic to cats.
Take a leaf to a nursery for ID. Refer to the included comprehensive list of cat-toxic plants. When in doubt, place the plant out of reach.
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