The brownish-orange film on waterfall rocks is typically a complex biofilm: a mix of brown and green algae, diatoms, bacteria, fungi, and trapped sediment. It's essentially the pond's "skin"—a natural, usually harmless community.
If the coating is thick, smelly, or associated with poor water quality (high nitrates, low oxygen), it may indicate excess nutrients. Otherwise, it's mostly aesthetic.
For more, see pond algae control.
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