A Houston pond (no fish/plants) has brown, gritty deposits on upper rock surfaces only. Lime-Away dissolves it; chlorine doesn't. Water source: city water run through a water softener. Rocks are large, flat, reddish.
Water softeners exchange calcium/magnesium for sodium — they do NOT remove iron. If your city water has iron (common in well water, but possible in municipal), the softener passes it through. When water cascades over rocks, iron oxidizes (rusts) and deposits as brown grit.
The reddish rocks likely contain iron minerals too, accelerating the process.
Splash zone = maximum evaporation = maximum mineral concentration. Submerged rocks stay wet, so iron stays dissolved.
For more on iron in water: water-research.net/iron.htm
Bottom line: Your softener isn't the problem—it's the iron in your source water. Filter it out or seal the rocks.
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