A pH of 4.6–4.7 is far too acidic for koi or goldfish. At this level, fish stress, gill damage, and impaired biological filtration occur. Your well water is the source, and simply topping off with it will keep the pond acidic.
While municipal water often has a higher, stable pH, the cost of filling a 2,000-gallon pond regularly can be high. Instead, treat the well water *before* it enters the pond, or buffer the pond itself.
Never raise pH more than 0.5 units per day when fish are present. A 1.0 unit change represents a 10-fold shift in acidity and can shock or kill fish. Test morning and evening; pH naturally fluctuates due to photosynthesis.
Install a carbon dioxide degassing column or aerate the well water in a holding tank before adding it to the pond. This drives off excess CO2, which forms carbonic acid. Also, establish a robust biological filter and add plenty of plants—they help stabilize pH naturally.
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